|
ИСТИНА |
Войти в систему Регистрация |
ИСТИНА ФИЦ ПХФ и МХ РАН |
||
Specific adsorption of ions and charge-distribution in an electrical double-layerстатья
Информация о цитировании статьи получена из
Web of Science
Статья опубликована в журнале из списка Web of Science и/или Scopus
Дата последнего поиска статьи во внешних источниках: 29 мая 2015 г.
- Авторы: Damaskin B., Kuznetsova L., Palm U., Vaartnou M., Salve M.
- Журнал: Journal of Electroanalytical Chemistry
- Том: 100
- Номер: 1-2
- Год издания: 1979
- Издательство: Elsevier Sequoia
- Местоположение издательства: Switzerland
- Первая страница: 365
- Последняя страница: 377
- DOI: 10.1016/0368-1874(79)85124-2
- Аннотация: The present paper is devoted to the analysis of the model of an electrical double layer on the electrode surface recharged by specifically adsorbed ions. The theoretical analysis is based on the experimental adsorption data obtained mainly on the solid bismuth electrode in aqueous and ethanolic solutions, and also on the mercury drop electrode in N-methyl-formamide solutions of binary or mixed surface-active electrolytes. It has been shown that the entrance of the counter-ions into the inner part of the double layer is a common phenomenon on electrode surfaces recharged by specifically adsorbed ions. An analysis of the calculation methods of the charge of the counter-ions in the inner layer has been carried out and a new calculation method of this quantity has been elaborated. Some general regularities of the entrance of the counter-ions into the inner layer have been established and the models of the charge distribution in the electrical double layer are analysed in the conditions of the specific adsorption of ions on electrodes. © 1979.
- Добавил в систему: Дамаскин Борис Борисович