|
ИСТИНА |
Войти в систему Регистрация |
ИСТИНА ФИЦ ПХФ и МХ РАН |
||
Macrocyclic Organic Peroxides: Constructing Medium and Large Cycles with O-O Bondsстатья
- Авторы: Barsegyan Yana A., Vil’ Vera A., Terent’ev Alexander O.
- Журнал: Chemistry (MDPI)
- Том: 6
- Номер: 5
- Год издания: 2024
- Издательство: MDPI
- Местоположение издательства: Basel, Switzerland
- Первая страница: 1246
- Последняя страница: 1270
- DOI: 10.3390/chemistry6050072
- Аннотация: Macrocycles bridge the gap between conventional small molecules and polymers. Drawing inspiration from successful carbon heteroatom-containing macrocycles, peroxide-containing macrocycles are gaining attention for enhanced bioactivity, potential chelating properties, and applications in energetic materials. This review presents the following strategies for the construction of cyclic peroxides with 10- to 36-membered frameworks: (1) the intramolecular iodocyclization of hydroperoxides, (2) the intermolecular cyclization of hydroperoxides with alkyl dihalides or carbonyls, (3) the acid-catalyzed rearrangements of ozonides or 11-membered cyclic triperoxides via oxy- or peroxycarbenium ions, and (4) the peroxidation of carbonyls targeting macrocyclic peroxides. The specific agents that allow for the selective construction of the medium and large cycles are also analyzed.
- Добавил в систему: Барсегян Яна Артуровна